Saturday, November 20, 2010

Question: How do you know when to add an ingredient?

In this post, still learning asks: Wonderful site! I've been looking to understand phases in a hair conditioner and just in general. I know oils goes in the oil phase and water in the water phase. Yet, I have seen other ingredients in each phase. How do you know what goes where? Thanks.

If you're making lotions, shampoos, conditioners, or any other bath and body products, the way to know what goes where depends upon two things - the solubility of the ingredient and how sensitive it is to heat. (I generally put that information into the posts on the ingredient! If I haven't, I really should!)

The heated phase of any product should be heated and held for 20 minutes at 70˚C. The cool down phase starts at between 45˚C to 50˚C. So if something can handle 70˚C or over or quite clearly needs to be melted - like SCI, our emulsifiers, beeswax - then we know we have to put them in the heated phase of something. The oil phase should contain all the things that are oil soluble - oils, butters, waxes, emulsifiers, thickeners, and so on. The water phase should contain all the things that are water soluble - water, hydrosols, proteins, and so on. Both phases should only contain those things that can handle 70˚C or higher.

Here's an example with conditioner. If we want to add BTMS-50, we know it must be melted and it is oil soluble, so it goes in the heated oil phase. If we want to add aloe vera, we know it's water soluble and can be heated, so it goes into the heated water phase.

But let's say you want to add honeyquat to the mix. I know it's water soluble, but it's heat sensitive, so I will put this in the cool down phase. What about polyquat 7? There aren't any disclaimers about heat with this ingredient, and I know it's water soluble, so I can add it to the heated water phase or cool down phase. If I want to add dimethicone or cyclomethicone, I know both are oil soluble but I'll add them to the cool down phase because they're heat sensitive.

What happens if you include something in the heated phase that should be in the cool down phase? A lot of things! You might inactivate the ingredient, it could give off a horrible smell (like honeyquat, for instance), it could destroy the emulsion, or you could change the skin feel of the product. The most likely outcome is that you will inactivate the ingredient - this is most common with preservatives and extracts - or, as you would find with a fragrance, it'll be gone by the time you combine the two phases.

What happens if you including something in the cool down phase that should be in the heated phase? This one's a lot tougher to answer because it could have no impact at all, it could ruin an emulsion, or it could have weird side effects you didn't expect. For instance, in this intense conditioner with all my conditioning agents, if you add the cetrimonium chloride to the heated phase (I generally put it in with the water), you get a stable emulsion. If you add it in the cool down phase, you might see some separation. If I add a ton of cold aloe vera to a lotion, it might mess with the emulsion. On the other hand, I have added polyquat 7 to the heated and cool down phases of my products with no effect.

What do you do with something that might have a temperature of 60˚C or falls between the heated and cool down phase? For the most part, throw that into the cool down phase, or watch that thermometer for the right moment (I generally put those in the cool down phase to make life easier).

So what you want to know about every ingredient is the solubility - oil or water soluble - and what temperature it can take! That will determine which of the three phases you would include your ingredient!

Hope this answers your question (and I love your name - we're all still learning no matter how much we think we know)!


Meaue said...

Perfect explanation - this helps me a lot too!

Anonymous said...


After multiple experiments, cetrimonium chloride belong to heated phase or cooling phase?

Susan Barclay-Nichols said...

Hi Anonymous! You can add the cetrimonium chloride to either phase, but I think the heated phase is the best choice to avoid separation in your conditioners!

lynnie said...

but what about where there's controversy? like raw honey? where some people say Pasteurized honey isn't the same as raw honey and heating it affects it's properties, would that be a personal choice? I would personally be inclined to add it in the cool down phase, but you know much more about chemistry than I do. I want to do that but want to try and make sure it won't mess things up.

Susan Barclay-Nichols said...

Hi Lynnie. What properties are you hoping to obtain from the honey? And I guess the question is - is honey heat sensitive? No, it's not. So you can add it to the heated water phase without problem.

Tiffany Jolly said...

Hi Susan!!! I absolutely love your blog and the information you provide! You are so smart and objective! So my first question is about the cool down phase. The stuff you add in this phase do you just add it when the temperature is right or do you dilute it with water or oil first then set it aside? Then add it when the lotion has cooled? I really may be nuking this but I can't seem to find anything on the subject?

Second question. Can you fully replace the water in a lotion with aloe vera juice or a hydrosol? I have been trying to find an answer for this but have come up empty handed.

~Tiffany J

Susan Barclay-Nichols said...

Hi Tiffany! I'm answering your question today's Weekday Wonderings. I encourage you to click on the link to learn more!

As an aside, I encourage you to check out the newbie section of the blog as I break down each section of a lotion and explain why we do what we do. I hope it's interesting reading. (I know I enjoyed writing it!)

Thanks for writing!

martacat said...

Hi Susan. You are such an invaluable resource. I have made three lotions so far and the only cool-down ingredient has been the preservative. Should each cool-down ingredient (e.g. preservative, honeyquat, dimethicone) be kept separate from the other ones? Or, can they be held in a single vessel before adding to the cooled emulsion?

Susan Barclay-Nichols said...

Hi Martacat! Add the entire cool down phase directly to the rest of the product. They are generally tiny bits of things, and you'll lose a lot when you pour it into the container. Just put everything directly from its original bottle into the lotion.